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Annie Ulvbane. Ekonomi/Administration. Maila Annie. – When tough is not enough! THE increased reactivity of a solid during and as a consequence of a crystalline transformation is commonly known as the Hedvall effect 1–3. In a wider sense this effect may include increased The increased reactivity of a solid near a crystal transformation is known as the Hedvall effect. Abstract.

Hedvall effect

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JOURNAL OF CATALYSIS 33, 138-141 (1974) The Hedvall Effect in the Decomposition of Hydrogen Peroxide on Single Crystals of a-Cr203 The kinetic parameters of certain cata- lyzed reactions depend on the magnetic state of the ferromagnetic (1, 2) and anti- ferromagnetic (S-5) solids catalyzing them (the Hedvall effect).* Looking for Hedvall effect I? Find out information about Hedvall effect I. A discontinuous change in the temperature dependence of the chemical reaction rate of certain substances at the Curie temperture. called Hedvall effect [l, 21 has been discovered in 1934. Meanwhile the experimental evidence includes as different processes as catalytic reactions [3,4], oxidation [5-81, sublimation [9] and desorption [lo].

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https://doi.org/10.1007/BF00549714. Download citation. Issue Date: May 1969.

Hedvall effect

A case study of a polymorphic transition in chlorpropamide T. N. Drebushchak, A. A. Ogienko and E. V. Boldyreva, CrystEngComm , 2011, 13 , 4405 The increased reactivity of a solid near a crystal transformation is known as the Hedvall effect. Hedvall 2 showed that calcium oxide would react with silver nitrate at a temperature considerably 1974-04-01 · A comparison with the investigations cited above (7-4) in which the Hedvall effect II is established shows an interesting pe- culiarity in all cases: irrespective of the catalyst nature (metal or semiconducting) and of the different magnetic ordering (ferro- or antiferromagnetic), the tempera- ture dependence of the rate constant be- comes steeper with the transition into the paramagnetic state (i.e., an increase in the activation energy is observed). THE increased reactivity of a solid during and as a consequence of a crystalline transformation is commonly known as the Hedvall effect 1-3 . In a wider sense this effect may include increased reactivity near a transition point. The increased reactivity of a solid near a crystal transformation is known as the Hedvall effect. Hedvall2 showed that calcium oxide would react with silver nitrate at a temperature considerably lower than the ``characteristic reaction temperature''.
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Hedvall effect

In a wider sense this effect may include increased ‘Hedvall effect’ in cryogrinding of molecular crystals.

Hedvall2 showed that calcium oxide would react with silver nitrate at a temperature considerably lower than the ``characteristic reaction temperature''. DOI: 10.1007/BF00549714 Corpus ID: 135757747.
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For Ni catalysts, experiments suggest the effect is related to a sudden increase in segregated surface C, a strong catalytic poison, at temperatures below ${T}_{C}$. I received my doctoral degree in 2012. My thesis dealt with the effects of forest management and nitrogen deposition on the flora in Swedish forest. I am now a researcher and teacher in forest ecology at the Southern Swedish Forest Research Centre, SLU at Alnarp. the Hedvall effect. There is a reaction between the mixture of each of these materials and AgNO 3 when they are heated through the transition temperature of silver nitrate (approximately1908C) and they quickly form a reciprocal pair (this involves the mutual ex-change between two molecules, for example, BaO + CaCO 3 ¼ CaO + BaCO 3 + Q). An A. Hedvall Effect J.A. Hedvall (3) stated "whenever solid sub-stances undergo a transformation involving the rearrange-ment of their atoms they pass through a state in which Ii they are more reactive than in the initial or final state." Examples of this is found in the reaction tempera-ture work of Hedvall, Htattig and other solid state chemists ‘Hedvall effect’ in cryogrinding of molecular crystals. A case study of a polymorphic transition in chlorpropamide The effect of grinding at ambient temperature and at 77 K (CryoMill Retsch) on the polymorphic transitions in α- and ε- chlorpropamide has been compared.